Coal, volcanism and Noah’s Flood
by Dr Andrew Snelling and John Mackay
The debate over the origin of coal seams was settled years ago in favour of in situ
(or autochthonous) formation from peats formed slowly in swamps of various descriptions.
One of the key factors in this ascendancy of the peat swamp model over the various
allochthonous (or transported) models was the recognition of so-called ‘fossil
forests’—tree stumps with roots and logs in apparent growth positions
on top of coal seams. The peat swamp model has not only become the basis of virtually
all studies on coal seam formation, but is now also the basis of studies on the
coalification of the plant constituents to produce the various coal macerals (e.g.
Diessel,1 Stach et al.2). For this reason considerable effort has been directed
towards the study of modern peat-forming environments (e.g. Martini and Glooschenko3) as a key to understanding the
peat precursors of coal and the coalification process itself. Even so, Prof. Martini
of Guelph University (Canada), a noted expert on modern peat-forming environments,
while giving his keynote address on the subject to a recent conference (the 1984
18th Newcastle Symposium organized by the Coal Geology Specialist Group of the Geological
Society of Australia) came to the question of the relationship between peat and
coal, and honestly admitted that he didn’t know what it was!
Unfortunately, the ascendancy of the gradualistic peat swamp model has led to neglect
of the evidence for the allochthonous, and catastrophic, deposition of coal seams.
Even with abundant evidence for contemporaneous volcanism resulting in volcanically
derived inter-seam sediments, such coals are still viewed as having formed in peat
swamps that were periodically buried by volcanic debris. But the May 18, 1980 catastrophic
eruption of Mount St. Helens, U.S.A., provided an opportunity to witness the wholesale
destruction of forests by volcanism, and to study the deposition of this forest
debris in layers and as stumps with roots and logs in growth positions within pyroclastic
sediments, all reminiscent of depositional sequences in some coal basins. Furthermore,
recent artificial coalification experiments have been able to rapidly produce high
rank coals using clays as catalysts under conditions analogous to those existing
in and around volcanic centres.
The 1980 Mount St. Helens eruption

Figure 1. Location map of the Mount St. Helens area, Washington, USA, showing
the devastating effects of the May 18, 1980 eruption.
Click here
for larger image.
|
On Sunday morning, May 18, 1980, an estimated 10 megaton explosion blasted over
four cubic kilometres of rock material out of Mount St. Helens, U.S.A. The top 400
metres of the mountain were blown away. According to Lipman and Mullineaux4 a ‘directed blast was generated by massive
explosions that occurred when an enormous landslide released the confining pressure
on a shallow dacite cryptodome and its associated hydrothermal system. Propelled
by expanding gases and gravity, the mixture of gas, rock, and ice moved off the
volcano as a catastrophic, hot, ground hugging, turbulent pyroclastic cloud at velocities
of as much as 300 m/s Within minutes the directed blast had extended about 25 km
and carried off or knocked down all trees in its path.’ Over a radius of more
than 11 km the surrounding coniferous forests were flattened and a wall of ash,
mud and broken trees roared across nearby Spirit Lake and down Toutle River Canyon
(Fig. 1). This volcanic debris included enormous quantities of trees which had been
devastated and stripped of their branches and leaves.
Reporting the event, Fritz5 stated
that many of the trees from Mount St. Helens were transported many kilometres down
Toutle Canyon by ash and mud flows and deposited upright and at various other angles.
Fritz commented (and recorded by photography) that although all the blasted stumps
were devoid of branches, many still had large root systems. Some even retained fine
rootlets. This was true particularly for the shorter stumps which were deposited
upright in an apparent growth position. The longer logs wore often deposited horizontally
while some were in diagonal position.
As a result of his investigations, Fritz5 concluded:
(a) It is wrong to automatically assume that trees discovered in mud or volcanic
ash sediments grew in situ just because they are in apparent growth position
and show root structures; and
(b) The mud and ash-flow deposited trees in Toutle Canyon have much in common with
the petrified ‘forests’ of the Eocene Lamar River Formation in Yellowstone
National Park.
Thus Fritz postulated that such petrified ‘forests’ could have been
formed rapidly by the repetition of similar mechanisms to that observed at Mount
St. Helens, that is, they were not formed in situ despite their apparent
growth position. Fritz’s observations of the events at Mount St. Helens and
his conclusions indicate that the Toutle River event produced large deposits of
upright coniferous logs in situations where they could still bleed from their freshly
broken surfaces, but be unable to drop leaves or branches, since these had already
been blasted off.
Returning again to the Mount St. Helens eruption, after the violence had subsided,
a gigantic raft of broken logs and stumps floated on nearby Spirit Lake (see Fig.
1).6 Between the logs were the smaller
charred remains of bark, broken branches, woody splinters and anything else that
had not totally burned in the gas cloud that had poured down Mount St. Helens. The
mountain itself was a sterile grey, bare of life and covered only with loose ash
and pumice.

Figure 2. Idealized sketches of deposition in Spirit Lake, Mount St. Helens
area, Washington, USA. (a) Deposition of debris from, and by, the initial eruptive
blast. (b) Deposition of ash and organic debris by subsequent rainfall run-off.
Click here
for larger image.
|
Comparison of aerial photographs of Spirit Lake taken soon after the eruption with
those taken in late 1983 indicated that the size of the log raft had diminished
over those three years. Much of the material had become waterlogged and sunk to
the bottom. Many of the larger logs and stumps were still floating, and a significant
portion of them were floating vertically. This was particularly true of those with
large root areas still attached or with larger trunk bases.6
The same was true of many of the sunken logs, as investigated by skin divers McMillen
and White in late 1983.6 The bottom of Spirit Lake resembled an underwater
forest. Those tree stumps resting on the bottom, roots down and trunks vertical,
gave the appearance of having grown there. They were very easy to push around, but
rapidly returned to their vertical floating position. The skin divers reported that
where the lake was less than six metres deep, the bottom was devoid of debris, because
the sunken logs and fragments either had accumulated in the deeper parts of the
lake, or had been rapidly covered by more volcanic ash being washed into the lake.
In fact every new rainfall still brings an abundance of volcanic ash, mud and organic
debris into Spirit Lake, because the surrounding mountain-sides are still devoid
of new well-established vegetation.
Figure 2a is an idealized sketch of what the bottom of Spirit Lake is visualized
as looking like at present, particularly the deepest parts of the lake. There would
first be layers of ash, and rubble from the initial explosion, followed by an accumulation
of pine tree fragments such as the more resistant leaf debris, bark and wood splinters
which sank after floating for only a short time in the lake, all buried by ash and
mud. Much of this pine tree debris would be charred or burnt. On top of this layer
of ash would be further ash and mud (from later rainfall) with the larger sheets
of bark that have only recently pealed off the floating logs through bacterial action.
Logs and stumps, many in the root-down position and with bark peeled or blasted
off, would then be resting on the top of these layers with still further ash and
mud accumulating around them. It is not hard to visualize how increased run-off,
sedimentation, and/or further ash falls would deposit and more organic debris and
logs, and so add to this tern of sediment accumulation several times in succession
as depicted in Figure 2b.
Already one scientific field expedition has commenced investigation of the Spirit
Lake area as modern site of coal seam formation. An early report7 has confirmed the essential elements of the model
depicted in Figure 2. Many more pine logs are now floating vertically in the waters
of Spirit Lake, while the charred remains of other pine tree debris (bark and wood
splinters) lie buried in the volcanic ash and mud both on the lake’s bottom
and on the lake’s shores. The report indicates that some of this debris appears
to have already coalified.
Analogue of ancient rapid coal measure formation
Newcastle, N S.W, Australia

Figure 3. Generalized geological map of the Newcastle Coalfield, NSW, Australia
showing the location of Swansea Heads and Quarries Head.
Click here
for larger image.
|
In the coal measures at Newcastle, NSW, several sediment sequences similar to that
in the idealized diagrams of Figure 2 have been identified in outcrops at Swansea
Heads and Quarries Head (see Fig. 3).
The relevant coal seams in this area are the Upper and Lower Pilot Seams, seen in
Figure 4 with tree stumps protruding from them up into tuff
beds. These seams are stratigraphically located in the Boolaroo Sub-Group of the
Newcastle Coal Measures (Fig. 5). McKenzie and Britten8 describe the Upper and Lower Pilot Seams as a ‘series
of thin coal and carbonaceous plies with only generalized groupings into seams,
so that the relationship of their thicknesses and those of the interbedded sediments
to overlying and underlying seams cannot always be well defined Both seams are characterized
by their association with thick tuff beds which normally have a wide range of red,
green and black colours. … These tuffs contains abundant flakes of mica.
Where the two groupings are identifiable, the intervening Reid’s Mistake Formation
mostly consists of the Southampton Sandstone Member with associated shales and minor
tuff beds.’ The beds dip between 4° and 8° to the west.9 The Pilot Seams are not of economic significance
or quality. The Upper Pilot Seam, for instance, contains up to 28% ash.10
Diessel11 has described in detail
the section at Swansea Heads and Quarries Head. Figure 6 is
his generalized sketch of the relevant section, which may be closely compared to
the Quarries Head cliff outcrop shown in Figure 4. Diessel11 has divided
the Reid’s Mistake Formation between the Lower and Upper Pilot Seams into
four tuff sub-units and interpreted them as ash fall, pyroclastic surge, ash flow,
and pyroclastic surge deposits respectively, using the pyroclastic (ash) deposits
of the May 18, 1980 lens eruption4 as his model.
The site at Swansea Heads is a well known tourist spot and is referred to by Diessel,9
who made the comment that ‘one of the most interesting the area is the occurrence
of remnants of tree trunks, many of them in growth positions , on top of the Lower
Pilot Coal.’ That statement reflects the long-standing view held by many as
far David12 that the tree stumps
are in growth position. However, is not a universal opinion as Branagan and Packham13 indicate: ‘Some of the
stumps appear to be in the position of growth but this may be accidental.’
Figure 4. Tree stumps and logs in apparent growth positions at Swansea
Heads (a) (b), and Quarries Head (c). At Swansea Heads the stump (a) and log (b)
are in the ryholitic tuff above the Lower Pilot Seam. They are completely silicified,
apart from coalification of the former bark on the log. At Quarries Head the logs
sit on top of the Lower Pilot Seam (see also Fig. 6).
Figure 5. The stratigraphic sequence in the Newcastle Coal Measures (after
Crapp and Nolan10).
Click here
for larger image.
|
The vast number of tree stumps and logs include many in an upright position as well
as those in horizontal positions (see Fig. 4). The horizontal logs are usually coalified
and crushed, whilst the vertical logs often have at their bases coalified bark with
iron carbonate replacement of the interior woody tissue. The upper trunks of the
vertical logs which protrude high into the tuffs are often silicified, the woody
tissue being replaced by chalcedony. The tuff around these logs contains coalified
specks that have the characteristics of resinite or coalified resin.
Historically, the logs and stumps have been regarded as overwhelming evidence of
in situ formation of the coal seams, but the following observational evidence
argues strongly against the trees being in actual growth position:
(a) Whilst many of the stumps and logs are in vertical positions, they rarely exhibit
evidence of branching or leaf structures and are commonly fractured at their ends.
They are therefore identical to the logs and stumps produced by the Mount St. Helens
explosion and deposited with ash in both Spirit Lake and Toutle Canyon.
(b) Even as far back as 1907, David12 argued that these trees had-been
rapidly buried by an ash fall, and in support of his argument pointed to the presence
of resinites in the associated tuff. Since some of the vertical trees he referred
to were up to 30 feet or 10 metres tall, their excellent state of preservation indicates
that the entire 10 metres of ash and sediment were deposited quickly, that is, the
inter-seam sediments between the Upper and Lower Pilot Seams were rapidly and catastrophically
deposited, a conclusion acknowledged by Dresser111 by his discussion
of the origin of these inter-seam tuffs.
(c) The stumps and logs are found on the top of the coal seams and are not in the
coal. The root structures of the tree stumps rarely penetrate any depth into the
coal seams. David12:293 claimed this was because the precursor trees,
which have been identified as Dadaxylon, a relative of the Norfolk, Island Pine,
could not grow healthily ‘if immersed in peat’. This is a factual statement
which does not assist the argument that the tree stumps are in situ.

Figure 6. Generalized sketch of Reid’s Mistake Formation at Quarries
Head south of Newcastle showing its major sub-division (after Diessel11).
Click here
for larger image. |
(d) The classification of the stumps and logs as Dadaxylon supports the thesis that
the precursor trees were catastrophically destroyed. Dadaxylon is, in fact, the
name given to Araucaria pine trees when it is uncertain what specific name should
be given to pine trees that are recognized as Araucaria. In this case the reason
the name Dadaxylon has been given is that the stumps and logs rarely show any evidence
of leaf scars or branches, factors that are necessary for identification of Araucaria.14 The absence of these identifying
factors again indicates catastrophe, that is, the precursor trees were stripped
of these recognizable features in much the same way as the conifers on the slopes
of Mount St. Helens were stripped of their leaves, branches and some bark by the
force of the 1980 eruption’s blast.
(e) The coal upon which the logs and stumps are lying and the enclosing sediments
contain abundant evidence of Glossopteris flora, but a virtual absence of Araucaria
forest litter. This is an observation that even David12 commented was
strange if the Araucaria actually grew there.
(f) The coal and surrounding sediments show no conclusive evidence of bioturbation.
Even the commonly referred to vertebraria could be viewed as having been deposited
contemporaneously with the sediments.
(g) Analyses of the coalified bark of the logs, even those reported by David12
back in 1907, and analyses of the coal in the seams below the tree stumps and logs,
indicate that much of the coal in the seams is derived from, or has similar composition
to that of, the Araucaria bark. This suggests that the coal, while not containing
much evidence of Araucaria forest litter on its surface, does contain much Araucaria
bark throughout. Such a situation is inexplicable if the precursor trees are viewed
as the terminal growth, or the forest stage, of a peat swamp. Under terminal swamp
conditions, the Araucaria bark and litter should only be found on the surface of
the peat, since they would be deposited there only after the area had ceased to
be a swamp. Thus this evidence is far more consistent with a volcanism model, where
the bark debris is deposited throughout the sediments like those in Spirit Lake,
than with terminal growth on a forested swamp (refer to David,12 Crapp
and Nolan10).

Figure 7. Location of the Oakleigh mine in the Rosewood-Walloon Coalfield,
Queensland, Australia.
Click here
for larger image.
|
(h) If Nashar15 is correct when
she states that some of the vertical logs of the Lower Pilot Seam originally penetrated
up into the next seam of coal, then it is obvious that not only were the inter-seam
volcanic sediments deposited rapidly, but so also was the vegetable material in
the Upper Pilot Seam. This would have been necessary to ensure that the full lengths
of the vertical logs would be preserved, since such logs would not have been preserved
if they had been exposed for any length of time while the area slowly subsided and
new swamp conditions developed.
(i) The occurrence of many crushed and coalified logs in a horizontal position,
and sometimes of enormous length, is remarkably similar to the Mount St. Helens
situation.
(j) Finally, the association of the logs with the coal, and in particular their
interpretation as representing the remains of the in situ terminal forest
stage of a coal-forming peat swamp, is seriously challenged by the occurrence of
the widespread Awaba ‘fossil forest’ marker bed12 below the
Great Northern Seam, and approximately 60 m stratigraphically above the Upper Pilot
Seam (see Fig. 5). In this bed, silicified stumps and logs are
often discovered in apparent growth positions, but without any necessary association
with coal, in a chert formation that has great similarities petrologically to the
felsic volcanic ash flow in Toutle Canyon. It is clear that the Awaba trees could
not have grown in situ. The massive chert formation the logs are in does
not represent a ‘fossil’ soil. Furthermore, the absence of any other
vegetation or forest litter is another factor which is exceedingly strange if the
area is supposed to be a buried forest in which only logs and stumps and no other
vegetation whatsoever are preserved.
The conclusion is obvious. One cannot assume that simply because coalified plant
matter and coalified Dadaxylon logs are found together, they either grew in situ
or necessarily had any active on site ecological relationship. In other words, the
events at Mount St. Helens, both in Spirit Lake and along Toutle Canyon, imply,
as Fritz5 pointed out, that arguments for in situ tree growth
cannot in future be based only on the position of logs sediments. Thus it is our
contention that the logs and coal seams at Swansea Heads and Quarries Head in the
Newcastle area, and the Awaba marker bed above them are more readily and consistently
explained by invoking a rapid and catastrophic allochthonous origin using the Mount
St. Helens event as a model, rather than the buried peat swamp hypothesis.
Oakleigh, Queensland, Australia

Figure 8. Generalized stratigraphic column of the Walloon Coal Measures
in the Rosewood-Walloon Coalfield (after Cameron16).
Click here
for larger image.
|
At Oakleigh near Rosewood, Queensland (Fig. 7) coal is mined
from the Walloon Coal Measures. Figure 8 is a generalized stratigraphic column of
the Walloon Coal Measures, while Figure 9 shows the stratigraphy
at Oakleigh.16
Cranfield et al.17 describe
the Walloon Coal Measures as comprising mudstone, siltstone, fine-grained labile
calcareous sandstone, thin coal seams and minor limestone. They comment that ‘generally
the sandstone is fine-grained, thick bedded, and friable, and consists of feldspar
and black lithic grains of andesitic material in a montmorillonite matrix. Mudstone
occurs with sandstone and siltstone as thin interbeds or in thicker massive beds.
Kaolinite is the dominant clay mineral.’
In their general description of the depositional environment of the Walloon Coal
Measures in the Rosewood-Walloon area, Cranfield et al.17 noted
that ‘contemporaneous volcanism is indicated by the presence of fresh andesitic
fragments in sandstones, and by montmorillonitic claystones which may be altered
tuffs.’18
The Walloon coal seams themselves are generally regarded to have formed in situ.18
Gould19 commented that:
- The fine-grained sediments immediately overlying the majority of seams contain a
greater percentage of conifers.
- The bulk of the coal appears to be from conifer material.
- The coal-forming flora was dominated by araucarian conifers.
- Pine cuticles are very common in the coal.
- Resinite is an abundant maceral in some Walloon coals.
- Araucarian ovuliferous cone scales and various pollen cones are preserved.
- Massive conifer-like trunks of fossil wood exhibiting growth rings occur in the
Walloon Coal Measures.

Figure 9. The stratigraphic sequence in the Oakleigh coal mine near Rosewood
(after Cameron16 ).
Click here
for larger image.
|
Thus the Walloon coal has much in common with the coal in the Upper and Lower Pilot
Seams, including the presence of volcanic ash in the inter-seam sediments.
Cranfield et al.17 also indicate that fossil wood fragments
are features of the Walloon Coal Measures. Indeed, even small vertical logs have
been observed on top of some of the seams in the Oakleigh mine. Figure 10 illustrates
one particular log that was discovered in the tuffaceous sandstone above the topmost
seam (see Fig. 9). Both the fragmented nature of the broken log, and the character
of the sediments in which it was found, confirm that it is a drift log, that is,
it didn’t grow in situ but was deposited with the sediments enclosing
it. What is also significant about this log is that it has hard black coal on the
outside, and low quality, very woody brown coal and iron oxides on the inside. Many
places still show the presence of tree rings (and splinters). The presence of both
black coal and brown coal in the one log, and also the very fine lining of black
coal on either side of a clay-filled fracture that penetrates across the inside
of the log (see Fig. 10), quite clearly indicates that the
coalification of the wood in this log did not necessarily result from exposure to
temperature and pressure over a long period of time. Both these factors (temperature
and pressure) would have reached equilibrium throughout such a thin log over any
extended period of time. The presence of high rank black coal only around the outside
(and lining the fracture) indicates
(a) that the process of coalification was so rapid that there was insufficient time
for coalification conditions to reach equilibrium throughout the log, or
(b) that there was a difference in conditions between the outside and the inside
of the log which resulted in coalification advancing further around the circumference
of the log, or
(c) both of these conditions.
A very significant implication of these observations is that if coalification resulted
from the log being exposed to a rapid heating event, then this would also imply
that the sediments surrounding the log were not only rapidly heated, but they also
cooled rapidly: that is, they rapidly lost sufficient heat so as to drop below the
temperature at which the inside of the log would have also reached the same advanced
stage of coalification as the log’s outer circumference. In other words, there
was rapid heat loss on a regional scale.
Volcanism and rapid coalification

Figure 10a. A broken log found in tuffaceous sandstone above the topmost
coal seam at Oakleigh near Rosewood (see Fig. 9). A general
view of two pieces of the log which consist mainly of woody brown coal.
See Figure 10b.
|
The observations of a volcanic eruption at Mount St. Helens, the Toutle River ash
and mud flows which deposited conifer logs and roots in apparent growth positions,
and the Spirit Lake phenomenon which produced vertical growth position conifer logs
with or without roots in tuffaceous sediments and conifer bark rich debris have
been shown to be quite clearly related as depositional models to the vertical pine
tree logs with a pine bark and clay-rich coal and jutting into overlying tuff layers
at Swansea and Quarries heads, the Awaba ‘fossil forest’ marker bed
of similar pine logs but in chert largely devoid of other vegetable matter, and
the Oakleigh drift log consisting of both black and brown coal that was discovered
in tuffaceous sandstone above seams which are full of coalified pine cuticles. This
relationship highlights a point made by Dryden,20
and remade by Hayatsu et al.21
that ‘there had been no incontrovertible evidence to support any theory of
coalification.’ This has been stated here because the listed observations
strongly imply that not only can large quantities of carbon-rich sediments be accumulated
rapidly in catastrophic conditions, but that the same sediments can be coalified
rapidly.
The Mount St. Helens volcanic eruption as a depositional model for coals appears
particularly obvious from the widespread occurrence of volcanic tuffs and associated
clay minerals resulting from devitrification of tuffs in the coals and inter-seam
sediments of the Newcastle and Rosewood-Walloon coalfields. Where tuffs are not
apparent, their previous existence is often suspected because of the widespread
distribution of clay minerals which potentially have been derived from ash falls.11,17
Since depositional relationship between these coals and volcanism can thus be established
by the fact that the majority of the clays associated with these coals are common
derivatives of volcanic ash, then similarly a relationship between volcanism and
rapid coalification of these seams can be established on the basis of laboratory
experiments in which it has been shown that such clays seem to act as catalysts
for the rapid coalification of carbon-rich materials. Furthermore, the non-relationship
of peat to coal can thereby be demonstrated, since the present of large amounts
of clay throughout these coal seams disassociates them from being descendants of
peat swamps, particularly cold environment peat swamps, which are virtually devoid
of clays.
Mechanisms for rapid coalification

Figure 10b. A closer view of one piece showing, from left to right, tuffaceous
sandstone still clinging to the log, bituminous (black) coal, and the woody brown
coal of the bulk of the log.
See Figure 10c.
|
Karweil22 reported that he had produced
artificial coal by rapidly applying vibrating pressures to wood. Subsequently Hill23 reported that he had also manufactured
artificial coal through rapid application of intense heat. While both these studies
used simulated conditions that are applicable to coalification in areas of tectonism
and volcanism, such as the coal seams at Newcastle and Oakleigh, recent work by
Hayatsu et al.,21 is even more applicable. In their study, Hayatsu
and his colleagues at the Argonne National Laboratory, Illinois, USA made simple
coals by heating lignin to about 150°C in the presence of montmorillonite or
illite clays. Running that procedure for periods ranging from two weeks to nearly
a year, they discovered that longer heating times produced higher rank coals, and
found that the clays appear to serve as catalysts that speed the coalification reaction,
since the lignin is fairly unreactive in their absence.
In summary, the relevant aspects of the work of Hayatsu et al.21
are:
- Softwood lignin heated with clay minerals (particularly montmorillonite) at 150°C
for two to eight months in the absence of oxygen was readily transformed into insoluble
materials resembling coals of various ranks.
- Longer reaction times produced materials resembling vitrinites of higher rank.
- Simple pyrolysis of lignin without clay at 350 to 400°C yielded only char (fusinite?).
- Using kaolinite or illite, independently or mixed with montmorillonite, produced
similar results.

Figure 10c. A closer view of the other piece showing, in cross section,
the bituminous (black) coal on the log’s circumference and along a clay filled
fracture.
|
They concluded, therefore that natural clay minerals are important for coalification
because they act as catalysts.
They also noticed that:
(a) in the presence of clay activated by acid, the reaction of lignin to form coaly
materials was highly accelerated, even at only 150°C (four weeks instead of
two to four months!); and
(b) loss of catalytic action of clays occurred when the reaction was carried out
in the presence of air.
Thus their overall conclusion was that coal macerals can be produced rapidly from
biological source material by a clay-catalyzed thermal reaction in periods of only
two to four months (sometimes one month).
Tables 1 and 2 summarize the experiments conducted by Hayatsu et al.21
It should be noted from Table 1 that samples AV1 and AV4 produced
coal materials ranging from low rank over two months to high rank over eight months.
By comparison, sample AVOX was heated in the presence of air and produced no noticeable
coal products after two months, while sample PL3, which was a 400°C experiment
over an hour, produced only char material. Note also the results of experiments
2 and 3 in Table 2. When no acid was used the coalification
time was two months, while acid-activated coalification took only 28 days. Furthermore,
temperatures lower than 150°C have so far not been tried in these experiments.
|
Table 1. Summary of Artificial Coalification Reactions21 |
|
Product Designation |
Sample |
Clay |
Temp. °C |
Time |
|
AV1 |
Lignin |
Yes |
150 |
2 Mo. |
|
AV2 |
Lignin |
Yes |
150 |
4 Mo. |
|
AV3 |
Lignin |
Yes |
150 |
6 Mo. |
|
AV4 |
Lignin |
Yes |
150 |
8 Mo. |
|
AVOX |
Lignin/Air |
Yes |
150 |
2 Mo. |
|
AP |
Lignin |
Yes |
350 |
30 Min. |
|
PL1 |
Lignin |
No |
350 |
30 Min. |
|
PL2 |
Lignin |
No |
350 |
60 Min. |
|
PL3 |
Lignin |
No |
400 |
60 Min. |
|
PC1 |
Cellulose |
No |
350 |
30 Min. |
|
PC2 |
Cellulose |
No |
350 |
60 Min. |
|
PC3 |
Lignin/Cellulose |
No |
350 |
60 Min. |
|
AA1 |
Fatty Acids (F1) |
Yes |
200 |
4 Mo. |
|
AA2 |
Fatty Acids (F1) |
Yes |
200 |
6 Mo. |
|
AA3 |
Fatty Acids (F2) |
Yes |
200 |
4 Mo. |
|
Table 2. Effect of Clay Mineral
as Catalyst for Artificial Coalification of Softwood Lignin21
|
|
|
|
|
Yield Wt% |
Insoluble Product |
|
Run |
Catalyst |
Condition |
Solvent Extractable |
Insoluble Product |
H/C |
O/C |
|
0 |
None |
(Starting Material) |
|
|
1.08 |
0.33 |
|
1 |
None |
150°C |
2 Mo. |
2.7 |
91.5 |
1.04 |
0.32 |
|
2 |
Montmorillonite |
150°C |
2 Mo. |
13.5 |
68.4 |
0.94 |
0.28 |
|
3 |
Acid Activated Montmorillonite |
150°C |
28 D. |
9.1 |
76.3 |
0.77 |
0.16 |
|
4 |
Montmorillonite/A1Br3(1:0.05) |
150°C |
24 Hr. |
15.3 |
62.0 |
0.92 |
0.25 |
|
5 |
A1Br3 |
120°C |
24 Hr. |
22.3 |
59.4 |
0.86 |
0.26 |
Clays, coals and volcanism
The significance of the work of Hayatsu et al.21 is in the role
of clays as catalysts since the clay minerals illite, montmorillonite, and kaolinite
are the most common inorganic mineral constituents of coals. In fact, clays often
account for up to 60% or 80% of the total mineral matter associated with the plant
debris in coal. Clays in coal are found as:2
- Fine inclusions
- Layers
- Partial or complete fillings of plant cell cavities, particularly in vitrinite.
In this case the clay is usually homogeneous kaolinite.
|
Table 3. Variation of Ash Yield (per cent) in Various
Coal types (Data from Stach et al.2) |
|
|
Vitrians |
Clarains |
Duro-Clarains |
Durains |
Fusains |
|
Australia (Permian) |
<2—14 |
2—22 |
2—22 |
2—22 |
2—22 |
|
Indian (Permian) |
<2—12 |
2—22 |
2—22 |
4—42 |
<2—30 |
|
North America (Carboniferous) |
<2—12 |
<2—16 |
n.a. |
2—20 |
4—20 |
|
British (Carboniferous) |
2—6 |
2—12 |
n.a. |
<2—16 |
2—3 |
Another interesting observation on clays in coal is the differing percentages of
clay in the different types of coal (See Table 3). While fusains
and durains normally contain a far greater percentage of mineral matter than vitrains
and clarains, the mineral content of vitrains is almost totally clay. Furthermore,
in most Southern Hemisphere coals, clays predominate over other types of inorganic
matter (e.g. see Ward24). In Australian coals even after washing over
half the original clay content is still present, indicating that the clay is therefore
homogeneously distributed throughout the coal.
|

Figure 11. The effect of rising temperatures during metamorphism of the
clay minerals usually found in coal seams (Data from Stach et al.2).
|
Now these clays are also commonly derived from volcanic ash. The same clay minerals,
principally kaolinite,24 can be found in the form of tonsteins which
because of their widespread nature, have become increasingly important as marker
beds in coal measure sediments. Such tonsteins are not only important as marker
horizons for particular bands in a single coal seam, but for seam correlation in
a coal basin or district, and even in adjacent coal basins over distances of several
hundred kilometres as has been experienced in Northern European coal belts.2
It has been suggested that these tonsteins originated as volcanic ash falls.2,11,25
The presence of the clays, particularly kaolinite, also indicates that the temperatures
involved in coalification must have been less than 200°C. At and above this
temperature the common clay minerals are metamorphosed, e.g. kaolinite to pyrophyllite
(see Fig. 11). This underlines the reasoning behind Hayatsu et al.’s
investigation of clay-catalyzed coalification at low temperatures.21
The weight of evidence (observation and data) suggests that the clays found in coals
and inter-seam sediments are involved in the coalification reactions and are important
indicators of the conditions during both seam deposition and seam coalification.
The clays strongly suggest related nearby volcanism and disallow cold climate swamp
and peat-forming environments as precursors to the coals.
Clays and peat swamps
The widespread presence of clays in coals has led advocates of the peat swamp hypothesis
to suggest that the clays are derived from clays and feldspar debris washed into
swamps during flood periods. However this suggestion ignores the observation that
in most acid swamp environments, clays will flocculate and not settle to the bottom.
Such a suspended state will not produce the homogenous distribution of clays throughout
the organic swamp debris and it most definitely cannot explain the clay bands consistently
traceable as marker horizons between adjacent coal basins.
But it is still necessary to account for the current coal structures with their
homogeneously distributed clays, particularly through the higher rank coals, so
can this have been achieved by chemical means, that is, by precipitation from incoming
surface waters, percolating ground waters, or the swamp waters themselves? Ward,24
for example, proposes several mechanisms whereby the clay minerals could have been
transported in solution as colloids, or as silica and alumina gels, to then precipitate
and crystallize within the structures of the coal-forming peat, but he then admits
that this mechanism does not explain some of the field and mineralogical evidence.
The inability of clay minerals to form within coals by such mechanisms and under
such conditions is dramatically illustrated by the presence of very pure, high grade
clays associated with brown coal deposits and yet quite distinct from them. For
example, the Latrobe Valley brown coal seams at Yallourn and Morewell, Victoria,
Australia, sit on pure white clay which has not ‘diffused’ into the
coal seams above or below them by such groundwater action.26
This is further confirmed by the virtual absence of aluminium silicates throughout
the brown coal.27
Finally, Martini and Glooschenko3 and Martini28
have shown and stated emphatically that cold climate peat swamps do not have clay
minerals in them. This conclusively indicates that such environments are not suitable
choices for precursors of coal seams.
Discussion
The application of these data on the relationship between clays and coal indicates
that the variables associated with coalification should probably be expanded to
include at least:
- The presence of the appropriate clay minerals to act as catalysts;
- The presence of the appropriate trace elements,
- The absence of catalytic poisons;
- The relevant pH;
- A rapid heat source of less than 200°C; and
- A variable pressure source similar to that associated with volcanism or tectonism.
This combination of variables successfully explains why non-anthracite coals are
sometimes found in high grade metamorphic rocks, showing that neither continuously
applied pressure nor heat have been the key factors. Similarly, it also explains
why some massive coal deposits are found as thick seams of low rank brown coal and
not as more mature higher rank black coals. One missing ‘ingredient’
in these brown coals is aluminium silicates (clays). A classic case is the Latrobe
Valley coals at Yallourn in Victoria, where thick brown coal seams are virtually
devoid of clays.26,27 By comparison, the thin Lower and Upper Pilot Seams
at Newcastle consist of higher rank black coals containing abundant clays.
This important relationship between clays and coalification also suggests why the
various coal types are associated with different clay combinations even within the
one seam, where temperature, pressure and pH had a high probability of being the
same. For example, vitrain has low mineral matter but a large percentage of this
mineral matter is clay, whereas fusain has high mineral matter but a much lesser
percentage of its mineral matter is clay. This higher mineral matter in fusain may
well act as a coalification inhibitor (or catalytic poison).
This same clay/coalification relationship can be taken a step further and applied
even to individual coalification events, such as that responsible for partial coalification
of the tree stumps in the Pilot Seams at Newcastle. Near the bases of these tree
stumps where the pH was lower due to the abundant adjacent vegetation debris, coalification
has occurred. Higher up the stumps where there was much less adjacent vegetable
material and higher amounts of siliceous volcanic ash, silicification has occurred.
Furthermore, at the bases of the tree stumps the ash surrounds the outside of the
stumps, so coalification of the lignin-rich bark has occurred, whereas solution
replacement occurred internally with the woody tissues being replaced by iron carbonate.
The coalification of only the bark near the bases of these tree stumps can now be
best explained as due to the thinner bark on the upper parts of the stumps having
been removed either by bacterial action similar to that seen in Spirit Lake, or
during the directed volcanic blast.
Likewise, the condition of the log found at Oakleigh can be explained on the assumption
that it has been subject to brief (and therefore rapid) clay-catalyzed thermal activity
around its circumference to produce high rank black coal, while the protected inner
portion of the log remained virtually unaltered. This thesis would also explain
why the Awaba tree stumps and logs, which are virtually devoid of accompanying vegetation
debris, have been silicified rather than coalified, whereas the tree stumps sitting
on the Pilot Seams have been coalified near their bases because of the accompanying
acid-generating vegetable material. If this thesis is correct, it is therefore feasible
to predict that tree stumps and logs deposited in tuffaceous sediments devoid of
accumulated acid-generating vegetation debris will most probably petrify. Thus it
is predicted that should appropriate conditions ensue the logs in the Toutle Canyon
ash flows will be more likely to petrify, while the logs being buried beneath the
waters of Spirit Lake will probably coalify around their external margins.
It should be obvious now that the explosive pyroclastic volcanism model can not
only be applied to the deposition of coal seams, but can be invoked to produce rapid
coalification of the same coal seams. The implication is that the whole process
from pine forests to coal seams was both catastrophic and extremely rapid. A series
of explosive pyroclastic eruptions from the one volcanic centre could flatten the
pine forests, bury the debris in ash, and then provide the rapidly applied pressures
(volcanic seismicity) and a rapid heat source at temperatures below 200°C (hot
ash, steam, etc.) to coalify the buried forest debris catalyzed by the clays buried
with the forest debris and to a lesser extent, by the clays in the overlying and
underlying tuffaceous muds and volcanic ash units. The evidence at both Newcastle
and Oakleigh is consistent with an explosive pyroclastic volcanism model for coal
seam formation.
Noah’s Flood
The relevance to Noah’s Flood of this explosive pyroclastic volcanism model
for the rapid destruction of whole forests, deposition of forest debris in seams,
and coalification of these seams should by now be obvious. The catastrophic effects
of volcanism and the associated flooding at Mount St. Helens were isolated to just
a small region that is hardly comparable to the extent measuring thousands of square
kilometres of many Australian coal basins, including the Sydney and Clarence Moreton
Basins (Newcastle and Walloon Coal Measures respectively). Any catastrophe that
produced these coal seams must have been on a greater scale than the impressive
explosive 1980 eruption of Mount St. Helens. The only large volcanic and water catastrophe
the world has experienced was Noah’s Flood, some 4,300 or so years ago.
During Noah’s Flood much of the water came from inside the earth. Genesis
7:11 records that the fountains of the deep broke open. If the earth opened, this
would probably have involved much volcanic activity as well. Even today up to 90%
of what comes out of volcanoes is water. Furthermore, in the last two decades many
springs have been discovered issuing forth prodigious amounts of hot (350°C)
salty water from deep-seated cracks and vents in volcanic rift zones on the ocean
floor.29 Such a global upheaval
as Noah’s Flood would have been catastrophic, for all the mountains on the
earth’s surface were covered with water (Genesis 7:18–23) and the earth’s
crust was broken up by earthquakes and volcanoes. The erosion and debris produced
would have been phenomenal.
This unique catastrophe would have devastated the entire forest and vegetation cover
of the earth’s surface. Some debris would been buried immediately by explosive
volcanic blasts, whereas other debris would have been carried off by the rising
waters as huge floating log rafts, only to be buried later as the logs became waterlogged
and sank, or further surges of volcanic ash and/or sediment-laden water buried them.
Thus whole coal measure sequences with multiple seams would have been deposited
rapidly. The heat flow produced by the catastrophic volcanism, crustal upheavals
(tectonism), rapid deep burial, circulating hot waters (hydrothermal activity) and
rising granitic magmas carrying radioactive elements would have been more than sufficient
to rapidly coalify the seams of forest debris, assisted particularly by the catalytic
action of the admixed clays present (as shown by the laboratory research).21
Given the catastrophic nature of Noah’s Flood, and the amount of vegetation
buried in today’s coal seams,30
it is thus entirely feasible that all of today’s coal seams were formed by
the global year long Noah’s Flood catastrophe and its aftermath.
Industrial applications
Finally, the concept of rapid coal seam formation in association with ancient explosive
volcanism, and the experimental work on clay-catalyzed rapid coalification has several
industry applications:
(1) Coal exploration—Explorers, seeking massive coal deposits should consider
exploring in areas of ancient explosive volcanism and tectonism. Target areas would
be those that consist of thick piles of tuffaceous sediments surrounding a dormant
caldera.
(2) Coal beneficiation—The possibility of using the concept of clay catalysis
for the potentially low cost upgrading of currently uneconomic brown coal deposits,
such as those in South Australia, should be seriously investigated. Even the Latrobe
Valley brown coals could potentially be upgraded to high rank black coals by mixing
the mined coal with the inter-seam clays and ‘cooking’ the mixture.
(3) Artificial coal preparation—Carbon-rich industrial waste products such
as those in the sawmilling, woodchip and sugar industries could potentially at low
cost be artificially coalified by utilizing clay as a catalyst. Such artificial
coals could even be made to customer specifications once the techniques have been
refined.
Summary and conclusions
The catastrophically deposited ash and mud flows along Toutle Canyon and in Spirit
Lake carried with them broken, conifer logs that were deposited or sank in apparent
growth positions, many with fine root structures. Further volcanic ash is still
the dominant sediment being washed over these buried logs. Thus the 1980 Mount St.
Helens eruption provides a model that is able to explain similar apparent growth
position tree stumps and logs in ancient coal deposits which are associated with
tuffaceous and/or clay-rich sediments. Upon this basis it has been concluded that
the tree stumps and logs on top of the Upper and Lower Pilot Seams and in the Awaba
‘fossil forest’ horizon at Newcastle did not grow in situ even
though they are found in apparent growth positions. The presence of both clays and
coalified pine bark, cuticles and debris throughout the associated Pilot Seams,
and in the coal seams at Oakleigh, indicate that the coal in these areas are not
the product of terminal pine forests on ancient swamps, since it would be impossible
then to explain the pine bark, cuticles and debris throughout the coal. Thus the
vegetable debris in the coal seams does not appear to have grown in situ.
Rather, it must have been washed into the depositional basins from the same forests
that the catastrophically deposited pine trees were stripped from by the explosive
volcanism. The coal therefore is allochthonous, and not autochthonous.
Such rapid accumulation of carbon-rich sediments in areas of volcanism also implies
the possibility of rapid seam formation. At Oakleigh the discovery in tuffaceous
sandstones above the coal seams of a broken log that has black coal around its circumference
and lining a clay-filled internal fracture, but only woody brown coal inside, provides
compelling evidence that temperature and pressure are not the key factors in coalification
and that coalification must have been rapid in such a volcanic setting. This widespread
association of volcanic ash and ash-rich sediments (particularly the tuffs and kaolinite-rich
tonstein marker beds) with coal seams full of allochthonous forest debris is an
indication that widespread volcanism was associated with past coal seam formation,
and provides evidence consistent with experimentally demonstrated rapid low temperature
(less than 200°C) clay-catalyzed coalification of such seams in contrast with
the slow formation, slow coalification autochthonous peat swamp hypothesis. The
absence of clay in many present day peat deposits is sufficient to throw further
doubt on the peat swamp hypothesis and should relegate such clay-free peats to be
viewed merely as an alternative state of preserved carbon-rich material. Such peat
deposits are thus not related to coal!
Applying this explosive pyroclastic volcanism model to the formation of coal deposits
world-wide, it is entirely feasible that all of today’s coal seams were formed
by the volcanism, flooding, erosion, deposition, tectonism and hydrothermal activity
during the global year-long Noah’s Flood catastrophe and its aftermath.
Related articles
References
- Diessel, C.F.K., Coal Geology, Australian Mineral Foundation,
Adelaide, 1980. Return to text.
- Stach, E., Mackowsky, M.-Th., Teichmuller, M., Taylor, G.H., Chandra,
D. and Teichmuller, R., Textbook of Coal Petrology, Gebruder Bortraeger,
Berlin and Stuttgart, 3rd Edition, 1982. Return to text.
- Martini, I.P. and Glooschenko, W., Cold climate environments of
peat formation in Canada, Proceedings of the Eighteenth Newcastle Symposium on Advances
in the Study of the Sydney Basin, pp 18–28, 1984. Return to
text.
- Lipman, P.W. and Mullineaux, D.R. (Editors), The 1980 Eruptions
of Mount St. Helens, Washington, U.S. Geol. Survey, Professional Paper 1250,
1981. Return to text.
- Fritz, W.J., Stumps transported and deposited upright by Mount
St. Helens mud flows, Geology 8:586–588, 1980. Return to text.
- Coffin, H.G., Erect floating stumps in Spirit Lake, Washington,
Geology 11:298–299, 1983. Return to text.
- Acts and Facts, Institute for Creation Research, San Diego,
pp. 1, 4, October 1984. Return to text.
- McKenzie, P.J. and Britten, R.A., Newcastle coal measures; in:
G.H. Packharn (Editor), The Geology of New South Wales, Journal Geological Society
Australia 16(l):339–350, 1969. Return to text.
- Diessel, C. F.K., Excursion Guide—Day 1; in: C. Herbert and
R. Helby (Editors), A Guide to the Sydney Basin, Geol. Survey N.S.W. Bull.
26, pp 459–472, 1980. Return to text.
- Crapp, C.E. and Nolan, R.C., Newcastle District; in: D.M. Traves
and D. King (Editors), Economic Geology of Australia and Papua New Guinea. 2. Coal,
Australasian Institute of Mining Metallurgy, Melbourne, Monograph 6,
pp 163–175, 1975. Return to text.
- Diessel, C.F.K., Excursion Synopsis for Excursion Number 2,
Eighteenth Newcastle Symposium on Advances in the Study of the Sydney Basin,
Department of Geology, The University of Newcastle, 1984. Return to text.
- David, T.W.E., Geology of the Hunter River Coal Measures,
New South Wales, Geological Survey NSW, Memoir G4, 1907. Return to text.
- Branagan, D.F. and Packham, G.H., Field Geology of New South
Wales, Science Press, Sydney, 1967. Return to text.
- Andrews, N.H., Studies in Palaeobotany, John Wiley &
Sons, New York, 1961. Return to text.
- Nashar, B., The Geology of the Hunter Valley, Jacaranda
Press, Brisbane, 1964. Return to text.
- Cameron, J.B., The Rosewood-Walloon coalfield, Geological
Survey Queensland Publication 344, 1970. Return
to text.
- Cranfield, L.C., Schwarzbock, H. and Day, R.W., Geology of the
Ipswich and Brisbane 1:250,000 sheet areas, Geological Survey Queensland Report
25, 1976. Return to text.
- Day, R.W., Whitaker, W.G., Murray, C.G., Wilson, I.H. and Grimes,
K.G., Queensland geology—a companion volume to the 1:2,500,000 scale geological
map (1975), Geological Survey Queensland Publication 383,
1983. Return to text.
- Gould, R.E., The coal-forming flora of the Walloon coal measures,
Coal Geology 1(3):83–105, 1980. Return
to text.
- Dryden, I.G.C., How was coal formed? Coke Gas
18:123–126, 181–184, 1956. Return to text.
- Hayatsu, R., McBeth, R.L., Scott, R.G., Botto, R.E. and Winans,
R.E., Artificial coalification study preparation and characterization of synthetic
macerals, Organic Geochemistry (in press), 1984. Return to text.
- Karlweil J., Kolloquim chemi und physik dar systinkhole, Erdol
und Kohle-Erdgas Petrochemie 18(7):565, 1965. Return
to text.
- Hill, G.R., Some aspects of coal research, Chemical Technology
May 1972, pp. 292–297, 1972. Return to text.
- Ward, C.R., Mineral matter in Australian bituminous coals,
Proceedings Australasian Institute Mining Metallurgy. 267:7–25,
1978. Return to text.
- Price, N.B. and Duff, P. McL.D., Mineralogy and chemistry of tonsteins
from Carboniferous sequences of Great Britain, Sedimentology 13:45–69,
1969. Return to text.
- George, A.M., Brockway, D.J., Stacy, W.O. and Kiss, L.T., The
origin of minerals, inorganics and sulphur in brown coals, Proceedings of the Eighteenth
Newcastle Symposium on Advances in the Study of the Sydney Basin, pp. 67–69,
1984. Return to text.
- Gloe, C.S., Latrobe Valley Coal-Fields, Victoria; in: D.M. Traves
and D. King (Editors), Economic Geology of Australia and Papua New Guinea. 2. Coal,
Australasian Institute Mining Metallurgy, Melbourne, Monograph 6,
pp 345–352, 1975. Return to text.
- Prof. LP. Martini, personal communication, Eighteenth Newcastle
Symposium on Advances in the Study of the Sydney Basin, April 28, 1984.
Return to text.
- Edmond, J.M. and Von Damm, K., Hot springs on the ocean floor,
Scientific American 284(4):70–83, 1983.
Return to text.
- Did you know? Creation 7(3), 1984. Return
to text.
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